27, Cobalt (Co)
Cobaltum, mhd. kobalt = Kobold |
Säure-Base-Verhalten:
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Säure/Base-Verhalten der Cobalt-Oxide: |
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Reaktionen mit: |
HF 100% |
H2SO4 conc. |
HCl 20% |
CH3COOH 25% |
H2O |
NH3 25% |
NaOH 10% kalt |
NaOH 50% heiß |
NaOH liq. 400°C |
CoO |
CoF2↓ |
CoSO4 |
CoCl2 |
(CH3COO)2Co |
Co(OH)2↓ |
Co(OH)2↓ |
Co(OH)2↓ |
NaCo(OH)3 |
Na4Co(OH)6 |
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Legende: |
Lösung |
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Unlöslich |
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sauer → neutral → alkalisch |
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pKS-Werte von Säure-Base-Paaren (HA + H2O ↔ H3O+ + A-) : |
Säurename |
Formel |
pKS-Wert |
Basenname |
Formel |
pKB-Wert |
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Tetracarbonylcobalt(-I)säure |
HCo(CO)4 |
1 |
Tetracarbonylcobaltat(-I)-Ion |
Co(CO)4- |
13 |
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Kobalt(II)-Ion |
Co2+ |
9.47 |
Hydroxo-Kobalt(II)-Ion |
Co(OH)+ |
4.53 |
Hydroxo-Kobalt(II)-Ion |
Co(OH)+ |
9.63 |
Kobalt(II)hydroxid |
Co(OH)2 |
4.37 |
Kobalt(II)hydroxid |
Co(OH)2 |
12.4 |
Trihydroxo-Cobaltat(II)-Ion |
Co(OH)3- |
1.6 |
Trihydroxo-Cobaltat(II)-Ion |
Co(OH)3- |
14.8 |
Tetrahydroxo-Cobaltat(II)-Ion |
Co(OH)42- |
-0.8 |
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Kobalt(III)-Ion |
Co3+ |
1.75 |
Hydroxo-Kobalt(III)-Ion |
Co(OH)2+ |
12.25 |
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